Here's how to add name tags in Picasa Web Albums:
- Navigate to the photo you'd like to tag.
- Hover over it and you should see 'Click to name.' If not, click the Add People
button and reposition and resize the outline over your contact's face. - Click the face outline, enter a name in the text field that appears, then click Apply.

Google+ users: By adding a name tag in Picasa Web Albums, you're also sharing the photo with the people you tag. Learn more
You can use the Picasa desktop software to quickly add name tags to multiple photos at once.

button and reposition and resize the outline over your contact's face.